Quality Control of 1-Phenylethyl acetateIn 2017, Yu, Wei;Zhou, Minghong;Wang, Tianqi;He, Zidong;Shi, Buyin;Xu, Yang;Huang, Kun published 《”Click Chemistry” Mediated Functional Microporous Organic Nanotube Networks for Heterogeneous Catalysis》. 《Organic Letters》published the findings. The article contains the following contents:
Azide-functionalized microporous organic nanotube networks (MONN) were prepared from graft copolymers of glycidyl methacrylate, DL-lactide, styrene, 4-(chloromethyl)styrene, and an isobutyric acid α-trithiocarbonate by Friedel-Crafts crosslinking with formaldehyde di-Me acetal followed by substitution with NaN3. 1,3-Dipolar cycloadditions of propargyl-substituted TEMPO and DMAP with the azide-functionalized MONN yielded MONN-bound TEMPO and DMAP. MONN-bound TEMPO and MONN-bound DMAP were recyclable catalysts for the chemoselective oxidation of alcs. to aldehydes and ketones and for the acetylation of alcs. with acetic anhydride to yield acetates, resp.; the TEMPO MONN was recycled ten times with no loss in yield and fourteen times with some (10-15%) decrease in yield.1-Phenylethyl acetate (cas: 93-92-5) were involved in the experimental procedure.
1-Phenylethyl acetate(cas:93-92-5) is a carboxylic ester. Quality Control of 1-Phenylethyl acetate It may be prepared by acetylation of methyl phenyl carbinol; from 1-bromoethylbenzene and silver acetate in acetic acid; from benzaldehyde by reacting with magnesium methyl bromide and subsequent acetylation.
Reference:
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