Ji, Guanfeng team published research on Angewandte Chemie, International Edition in 2022 | 870-50-8

Computed Properties of 870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., 870-50-8.

Glycerides are fatty acid esters of glycerol; they are important in biology, being one of the main classes of lipids and comprising the bulk of animal fats and vegetable oils. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate. Esters typically have a pleasant smell; those of low molecular weight are commonly used as fragrances and are found in essential oils and pheromones. Computed Properties of 870-50-8.

Ji, Guanfeng;Zhao, Liang;Wei, Jianwei;Cai, Junkai;He, Cheng;Du, Zenggang;Cai, Wei;Duan, Chunying research published 《 A Metal-Organic Framework as a Multiphoton Excitation Regulator for the Activation of Inert C(sp3)-H Bonds and Oxygen》, the research content is summarized as follows. The activation and oxidization of inert C(sp3)-H bonds into value-added chems. affords attractively economic and ecol. benefits as well as central challenge in modern chem. Inspired by the natural enzymic transformation, herein, we report a new multiphoton excitation approach to activate the inert C(sp3)-H bonds and oxygen by integrating the photoinduced electron transfer (PET), ligand-to-metal charge transfer (LMCT) and hydrogen atom transfer (HAT) events together into one metal-organic framework. The well-modified NAD (NAD+) mimics oxidized CeIII-OEt moieties to generate CeIV-OEt chromophore and its reduced state mimics NAD. via PET. The in situ formed CeIV-OEt moiety triggers a LMCT excitation to form the alkoxy radical EtO., abstracts a hydrogen atom from the C(sp3)-H bond, accompanying the recovery of CeIII-OEt and the formation of alkyl radicals. The formed NAD. activates oxygen to regenerate the NAD+ for next recycle, wherein, the activated oxygen species interacts with the intermediates for the oxidization functionalization, paving a catalytic avenue for developing scalable and sustainable synthetic strategy.

Computed Properties of 870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., 870-50-8.

Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics