Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate.Nitrate esters, such as nitroglycerin, are known for their explosive properties. Formula: C10H18N2O4.
Guo, Zheng;Xie, Jinglei;Hu, Tao;Chen, Yunrong;Tao, Houchao;Yang, Xiaoyu research published 《 Kinetic resolution of N-aryl β-amino alcohols via asymmetric aminations of anilines》, the research content is summarized as follows. An efficient kinetic resolution of N-aryl β-amino alcs. (S)-RCH(CHR1OH)NH(3-R2-C6H4) (R = Ph, 2-methylphenyl, 4-bromophenyl, naphthalen-2-yl, etc.; R1 = H, Me, Et, i-Pr; R2 = H, Me, OMe, Cl, F) and I (R3 = Et, i-Pr, t-Bu, Bn) has been developed via asym. para-aminations of anilines RCH(CHR1OH)NH(3-R2C6H4) with azodicarboxylates R3OC(O)N=NC(O)OR3 enabled by chiral phosphoric acid catalysis. Broad substrate scope and high kinetic resolution performances were afforded with this method. Control experiments supported the critical roles of the NH and OH group in these reactions.
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Formula: C10H18N2O4
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics