Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate.Nitrate esters, such as nitroglycerin, are known for their explosive properties. COA of Formula: C10H18N2O4.
Gerosa, Gabriela Guillermina;Schwengers, Sebastian Armin;Maji, Rajat;De, Chandra Kanta;List, Benjamin research published 《 Homologation of the Fischer Indolization: A Quinoline Synthesis via Homo-Diaza-Cope Rearrangement》, the research content is summarized as follows. We disclose a new Broensted acid promoted quinoline synthesis, proceeding via homo-diaza-Cope rearrangement of N-aryl-N’-cyclopropylhydrazines [e.g., I → II (76%) in presence of H3PO4 in 1,2-DCB at 170°]. Our strategy can be considered a homologation of Fischer’s classical indole synthesis and delivers 6-membered N-heterocycles, including previously inaccessible pyridine derivatives This approach can also be used as a pyridannulation methodol. toward constructing polycyclic polyheteroaroms. A computational anal. has been employed to probe plausible activation modes and to interrogate the role of the catalyst.
COA of Formula: C10H18N2O4, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., 870-50-8.
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics