Application In Synthesis of 1-Phenylethyl acetate《Tropolonate Salts as Acyl-Transfer Catalysts under Thermal and Photochemical Conditions: Reaction Scope and Mechanistic Insights》 was published in 2020. The authors were Lyons, Demelza J. M.;Empel, Claire;Pace, Domenic P.;Dinh, An H.;Mai, Binh Khanh;Koenigs, Rene M.;Nguyen, Thanh Vinh, and the article was included in《ACS Catalysis》. The author mentioned the following in the article:
Acyl-transfer catalysis is a frequently used tool to promote the formation of carboxylic acid derivatives, which are important synthetic precursors and target compounds in organic synthesis. However, there have been only a few structural motifs known to efficiently catalyze the acyl-transfer reaction. Herein, we introduce a different acyl-transfer catalytic paradigm based on the tropolone framework. We show that tropolonate salts, due to their strong nucleophilicity and photochem. activity, can promote the coupling reaction between alcs. and carboxylic acid anhydrides or chlorides to give products under thermal or blue light photochem. conditions. Kinetic studies and d. functional theory calculations suggest interesting mechanistic insights for reactions promoted by this acyl-transfer catalytic system. And 1-Phenylethyl acetate (cas: 93-92-5) was used in the research process.
1-Phenylethyl acetate(cas:93-92-5) is a carboxylic ester. Application In Synthesis of 1-Phenylethyl acetate It may be prepared by acetylation of methyl phenyl carbinol; from benzaldehyde by reacting with magnesium methyl bromide and subsequent acetylation; from 1-bromoethylbenzene and silver acetate in acetic acid.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics