Deng, Yifan;Zou, Yike;Yang, Chia-Ping H.;Houk, K. N.;Smith, Amos B. III published 《Total Syntheses of (+)-Peniciketals A-B and (-)-Diocollettines A Exploiting a Photoisomerization/Cyclization Union Protocol》 in 2021. The article was appeared in 《Journal of Organic Chemistry》. They have made some progress in their research.Product Details of 4707-47-5 The article mentions the following:
A late-stage photoisomerization/cyclization union tactic, in conjunction with Type I Anion Relay Chem. (ARC), permits enantioselective total syntheses and then biol. evaluation of (+)-peniciketals A (I) and B (II). The photochem. protocol was further showcased by an efficient three-step construction of the architecturally complex polycyclic skeleton found in (-)-diocollettine A (III). The mechanism and diastereoselectivity of the photochem. protocol have also been explored by both experiment and d. functional theory calculations To complete the study, the researchers used Methyl 2,4-dihydroxy-3,6-dimethylbenzoate (cas: 4707-47-5) .
Methyl 2,4-dihydroxy-3,6-dimethylbenzoate(4707-47-5) is used in biological study as role of androgens in inducing distinct response of epithelial-mesenchymal transition factors in human prostate cancer cells.Product Details of 4707-47-5
Reference:
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