Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 870-50-8, formula is C10H18N2O4, Name is Di-tert-butyl diazene-1,2-dicarboxylate.Nitrate esters, such as nitroglycerin, are known for their explosive properties. Name: Di-tert-butyl diazene-1,2-dicarboxylate.
Chauvier, Clement;Finck, Lucie;Hecht, Stefan;Oestreich, Martin research published 《 General Synthesis and Optical Properties of N-Aryl-N’-Silyldiazenes》, the research content is summarized as follows. Silyldiazenes ArN:NSiR3 were prepared by oxidation of the corresponding hydrazines with azodicarboxylate diesters with high yields and generality. While organo-substituted diazenes (R1-N:N-R2 with R = alkyl, aryl) are a well-studied class of compounds, much less is known about their heavier group 14 analogs, notably because of their perceived instability. We report herein a general oxidative protocol to prepare various N-aryl-N’-silyldiazenes by a fast and mild dehydrogenation of the corresponding silylhydrazines using di-tert-butylazodicarboxylate as an oxidant. The optical properties of these stable blue to purple silyldiazenes were also studied by UV/visible absorption spectroscopy and supported by TD-DFT calculations
870-50-8, Di-tert-butyl azodicarboxylate, also known as Di-tert-butyl azodicarboxylate, is a useful research compound. Its molecular formula is C₁₀H₁₈N₂O₄ and its molecular weight is 230.26 g/mol. The purity is usually 95%.
Di-tert-butyl azodicarboxylate is a reagent used in the electrophilic amination of β-keto esters catalyzed by an axially chiral guanidine. Building block in an enantioselective synthesis of 3,6-dihyropyridazines employing organocatalysts such a L-proline or (S)-2-pyrrolidinyl tetrazole. Utilized in the asymmetric Friedel-Crafts amination via a chiral organocatalyst.
Di-tert-butyl azodicarboxylate is a reagent used in the preparation of acyl hydrazinedicarboxylates via photoorganocatalytic hydroacylation of dialkyl azodicarboxylates with aldehydes in presence of phenylglyoxylic acid as photocatalyst., Name: Di-tert-butyl diazene-1,2-dicarboxylate
Referemce:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics