HPLC of Formula: 106-02-5《Synthesis of 23-, 25-, 27-, and 29-Membered (Z)-Selective Unsaturated and Saturated Macrocyclic Lactones from 16- and 17-Membered Macrocyclic Lactones and Bromoalcohols by Wittig Reaction, Yamaguchi Macrolactonization, and Photoinduced Decarboxylative Radical Macrolactonization》 was published in 2019. The authors were Iwasaki, Tomoya;Tajimi, Yuka;Kameda, Kenta;Kingwell, Callum;Wcislo, William;Osaka, Kazuyuki;Yamawaki, Mugen;Morita, Toshio;Yoshimi, Yasuharu, and the article was included in《Journal of Organic Chemistry》. The author mentioned the following in the article:
A new strategy for the synthesis of 23-, 25-, 27-, and 29-membered (Z)-selective unsaturated and saturated macrocyclic lactones from com. available 16- and 17-membered macrocyclic lactones and bromoalcs. by Wittig reaction, Yamaguchi macrolactonization, and photoinduced decarboxylative radical macrolactonization is described. The position of the unsaturated part in the macrocyclic lactones can be controlled by changing the number of carbons in the starting materials. This protocol can provide facile access to the desired large-ring (Z)-selective unsaturated and saturated macrocyclic lactones from simple starting materials.Oxacyclohexadecan-2-one (cas: 106-02-5) were involved in the experimental procedure.
Oxacyclohexadecan-2-one(cas:106-02-5) is a natural product found in Lonicera japonica and Angelica archangelica.HPLC of Formula: 106-02-5 It is a macrocyclic lactone that can be used as a flavoring agent and fragrance ingredient due to its musk flavor/odor.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics