Polyesters are important plastics, with monomers linked by ester moieties. Phosphoesters form the backbone of DNA molecules. 99769-19-4, formula is C8H9BO4, Name is 3-(Methoxycarbonyl)phenylboronic acid.Nitrate esters, such as nitroglycerin, are known for their explosive properties. Product Details of C8H9BO4.
Ambre, Ram;Wang, Ting-Hsuan;Xian, Anmei;Chen, Yu-Shiuan;Liang, Yu-Fu;Jurca, Titel;Zhao, Lili;Ong, Tiow-Gan research published 《 Directing Group-Promoted Inert C-O Bond Activation Using Versatile Boronic Acid as a Coupling Agent》, the research content is summarized as follows. A simple Ni(cod)2 and carbene mediated strategy facilitated the efficient catalytic cross-coupling of methoxyarenes with a variety of organoboron reagents. Directing groups facilitate the activation of inert C-O bonds in under-utilized aryl Me ethers enabling their adaptation for C-C cross-coupling reactions as less toxic surrogated to the ubiquitous haloarenes. The method reported enables C-C cross-coupling with readily available and economical arylboronic acid reagents, which was unprecedented and compared well with other organoboron reagents with similarly high reactivity. Extension to directing group assisted chemo-selective C-O bond cleavage and further application towards the synthesis of novel bifunctionalized biaryls was reported. Key to the success of this protocol was the use of directing groups proximal to the reaction center to facilitate the activation of the inert C-OMe bond.
99769-19-4, 3-Methoxycarbonylphenylboronic acid is a useful research compound. Its molecular formula is C8H9BO4 and its molecular weight is 179.97 g/mol. The purity is usually 95%.
3-Methoxycarbonylphenylboronic acid is a reactanct that has been involved in a variety of applications. For instance, it has been used in Suzuki-Miyaura cross-coupling, Iterative cross-coupling of boronate building blocks, cross-coupling with aryl/ alkenyl sulfonates, synthesis of symmetrical biaryls via CuCl catalyzed homocoupling, trifluoromethylation, and cyanation just to name a few of its many uses.
3-Methoxycarbonylphenylboronic acid is a boronate ligand that has been shown to have an interaction with the nitrogen atoms in amines. This compound is used for the Suzuki coupling reaction, which is a chemical reaction between an organoboron compound and an organic electrophile. 3-Methoxycarbonylphenylboronic acid has a helical structure that can be seen by FTIR spectroscopy and it has potent inhibitory activity., Product Details of C8H9BO4
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