Application In Synthesis of 6-Bromo-8-methylquinoline. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: 6-Bromo-8-methylquinoline, is researched, Molecular C10H8BrN, CAS is 178396-31-1, about Rhodium(II)-catalyzed regio- and stereoselective benzylic α-fluoroalkenylation with gem-difluorostyrenes. Author is Kong, Lingheng; Liu, Bingxian; Zhou, Xukai; Wang, Fen; Li, Xingwei.
Rhodium(III)-catalyzed mild benzylic α-fluoroalkenylation of 8-methylquinolines with gem-difluorostyrenes was developed. This reaction occurred via C-H activation and C-F cleavage and was applicable to a wide range of substrates, leading to the synthesis of Z-alkenyl fluorides under mild and redox-neutral conditions with high regio- and stereoselectivity.
This compound(6-Bromo-8-methylquinoline)Application In Synthesis of 6-Bromo-8-methylquinoline was discussed at the molecular level, the effects of temperature and reaction time on the properties of the compound were discussed, and the optimum reaction conditions were selected.
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