Synthetic Route of C36H30NO2P. Aromatic heterocyclic compounds can also be classified according to the number of heteroatoms contained in the heterocycle: single heteroatom, two heteroatoms, three heteroatoms and four heteroatoms. Compound: (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, is researched, Molecular C36H30NO2P, CAS is 415918-91-1, about Enantioselective Iridium-Catalyzed Allylic Amination of Ammonia and Convenient Ammonia Surrogates. Author is Pouy, Mark J.; Leitner, Andreas; Weix, Daniel J.; Ueno, Satoshi; Hartwig, John F..
Iridium-catalyzed, asym. allylation of ammonia as a nucleophile occurs with stereoselectivity to form a sym. diallylamine (R,R)-H2C:CHCH(Ph)NHCH(Ph)CH:CH2, and related allylation of the inexpensive ammonia equivalent potassium trifluoroacetamide or the highly reactive ammonia equivalent lithium di-tert-butyliminodicarboxylate forms a range of conveniently protected, primary, α-branched allylic amines RCHXCH:CH2 [R = Ph, 4-MeOC6H4, n-heptyl, 2-furyl, etc.; X=NHCOCF3, N(Boc)2] in high yields, high branched-to-linear regioselectivities, and high enantiomeric excess. The reactions of ammonia equivalent were conducted with a catalyst generated from a phosphoramidite containing a single stereochem. element.
Different reactions of this compound((11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine)Synthetic Route of C36H30NO2P require different conditions, so the reaction conditions are very important.
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