SDS of cas: 178396-31-1. The protonation of heteroatoms in aromatic heterocycles can be divided into two categories: lone pairs of electrons are in the aromatic ring conjugated system; and lone pairs of electrons do not participate. Compound: 6-Bromo-8-methylquinoline, is researched, Molecular C10H8BrN, CAS is 178396-31-1, about Copper-catalyzed intermolecular amidation of 8-methylquinolines with N-fluoroarylsulfonimides via Csp3-H activation. Author is Zhang, Xiaolei; Wu, Rui; Liu, Wanyi; Qian, Dang-Wei; Yang, Jinhui; Jiang, Pengju; Zheng, Qing-Zhong.
An efficient copper-catalyzed C-H amidation of 8-methylquinolines RC9H5N-8-Me (R = 5-halo, 5-Me, 6-halo, 6-Me, 7-halo, 7-Me, 7-MeO) with N-fluoroarylsulfonimides FN(SO2Ar)2 (Ar = Ph, 4-MeC6H4, 4-NO2C6H4, 4-FC6H4) via Csp3-H activation is described. The reaction proceeds with high functional group tolerance, providing a novel approach to valuable 8-quinolinemethanamine derivatives in the absence of an addnl. oxidant.
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