Liu, Bingxian; Hu, Panjie; Zhou, Xukai; Bai, Dachang; Chang, Junbiao; Li, Xingwei published the article 《Cp*Rh(III)-Catalyzed Mild Addition of C(sp3)-H Bonds to α,β-Unsaturated Aldehydes and Ketones》. Keywords: rhodium catalyzed addition carbon hydrogen bond unsaturated aldehyde ketone; directing group benzylic allylic carbon hydrogen bond addition reaction.They researched the compound: 6-Bromo-8-methylquinoline( cas:178396-31-1 ).Application In Synthesis of 6-Bromo-8-methylquinoline. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:178396-31-1) here.
A Rh(III)-catalyzed addition of benzylic C(sp3)-H bond to α,β-unsaturated ketones/aldehydes has been realized, leading to efficient synthesis of γ-aryl ketones/aldehydes. This atom-economic reaction proceeded under mild and redox-neutral conditions with a broad substrate scope. Besides benzylic C-H, allylic C-H bonds are also applicable when assisted by O-Me ketoxime directing groups.
Different reactions of this compound(6-Bromo-8-methylquinoline)Application In Synthesis of 6-Bromo-8-methylquinoline require different conditions, so the reaction conditions are very important.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics