Most of the compounds have physiologically active properties, and their biological properties are often attributed to the heteroatoms contained in their molecules, and most of these heteroatoms also appear in cyclic structures. A Journal, ACS Catalysis called Mild Acylation of C(sp3)-H and C(sp2)-H Bonds under Redox-Neutral Rh(III) Catalysis, Author is Yu, Songjie; Li, Yingzi; Kong, Lingheng; Zhou, Xukai; Tang, Guodong; Lan, Yu; Li, Xingwei, which mentions a compound: 178396-31-1, SMILESS is CC1=CC(Br)=CC2=C1N=CC=C2, Molecular C10H8BrN, Synthetic Route of C10H8BrN.
Carbonyl groups are ubiquitous in functional mols. Although C-H bond acylation has been well-studied via different mechanisms, transition-metal-catalyzed redox-neutral C(sp3)-H acylation under mild conditions is unprecedented. In this work, ketene is designed as a acylating reagent for both C(sp3)-H and C(sp2)-H bonds under Rh(III) catalysis, affording a diverse array of carbonyl compounds in high yields and high atom economy under mild conditions.
In some applications, this compound(178396-31-1)Synthetic Route of C10H8BrN is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics