The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: 6-Bromo-8-methylquinoline, is researched, Molecular C10H8BrN, CAS is 178396-31-1, about Rhodium(III)-catalyzed alkenylation reactions of 8-methylquinolines with alkynes by C(sp3)-H activation, the main research direction is methylquinoline alkyne alkenylation carbon hydrogen bond activation rhodium catalyst; allyl quinoline preparation mol crystal structure; CH activation; alkynes; regioselectivity; rhodium; synthetic methods.Safety of 6-Bromo-8-methylquinoline.
The alkenylation reactions of 8-methylquinolines with alkynes, catalyzed by [{Cp*RhCl2}2], proceeds efficiently to give 8-allylquinolines in good yields by C(sp3)-H bond activation. These reactions are highly regio- and stereoselective. A catalytically competent five-membered rhodacycle was structurally characterized, thus revealing a key intermediate in the catalytic cycle. The structures of the compounds were determined by spectroscopic data and confirmed by single crystal x-ray diffraction anal. of 8-(2,3-diphenylallyl)quinoline (I) and pentamethylcyclopentadienylchlororhodium complex of 8-methylquinoline (II). The crystallog. data were deposited at the Cambridge Crystallog. Data Center as supplementary publication number CCDC 978941 for I and CCDC 978942 for II.
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