Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 323196-43-6, is researched, SMILESS is O=C1N(C)C(C)(C)N[C@@H]1CC2=CC=CC=C2.[H]Cl, Molecular C13H19ClN2OJournal, Polymer Chemistry called Immobilization of MacMillan catalyst via controlled radical polymerization: catalytic activity and reuse, Author is Moore, Beth L.; Lu, Annhelen; Longbottom, Deborah A.; O’Reilly, Rachel K., the main research direction is MacMillan catalyst Diels Alder reaction kinetics cyclopentadiene trans hexenal; tyrosine methacrylate catalyst RAFT polymerization DEGMA MacMillan.Product Details of 323196-43-6.
The MacMillan catalyst is an established organocatalyst capable of catalyzing a variety of organic reactions. Through the synthesis of a novel monomer containing the MacMillan catalytic functionality, a variety of copolymers were synthesized with the comonomer, diethylene glycol Me ether methacrylate (DEGMA). Reversible addition-fragmentation chain transfer (RAFT) polymerization was used for the synthesis of these functional polymers with good control over mol. weight, catalyst incorporation and polydispersity. These polymers showed lower critical solution temperature (LCST) behavior where the cloud point is dependent upon the degree of catalyst incorporation and catalyst loading also has an effect on the Tg of the copolymers. The catalytic activity of the functional copolymers is demonstrated by the Diels-Alder reaction between cyclopentadiene and trans-hexen-1-al and shows enantioselectivity close to those previously reported by MacMillan. The polymers can be reused in multiple Diels-Alder reactions via a pseudo continuous process, maintaining high conversion and enantioselectivity throughout the cycles.
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Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics