Steib, Philip; Breit, Bernhard published the article 《Concise Total Synthesis of (-)-Vermiculine through a Rhodium-Catalyzed C2-Symmetric Dimerization Strategy》. Keywords: vermiculine total synthesis rhodium catalyzed enantioselective dimerization; Wacker-type oxidation; antibiotics; dimerization; metathesis; total synthesis; vermiculine.They researched the compound: (((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine)( cas:32305-98-9 ).Application In Synthesis of (((4R,5R)-2,2-Dimethyl-1,3-dioxolane-4,5-diyl)bis(methylene))bis(diphenylphosphine). Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:32305-98-9) here.
A short and efficient synthesis of the C2-sym. antibiotic (-)-vermiculine (I) by utilizing an enantioselective catalytic one-step dimerization methodol. as key-step to construct the core structure is reported. The late-stage modifications feature a double metathesis homologation followed by a double Wacker-type oxidation These key-steps allowed the synthesis of vermiculine in only seven steps, starting from com. available building blocks.
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