Related Products of 415918-91-1. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, is researched, Molecular C36H30NO2P, CAS is 415918-91-1, about Palladium-Catalyzed Asymmetric [3+2] Cycloaddition of Trimethylenemethane with Imines. Author is Trost, Barry M.; Silverman, Steven M.; Stambuli, James P..
The transition metal-catalyzed trimethylenemethane [3+2] cycloaddition provides a direct route to functionalized heterocycles. Herein, the authors describe a catalytic, asym. protocol for the reaction between 3-acetoxy-2-trimethylsilylmethyl-1-propene and various imines. The corresponding pyrrolidines were obtained in excellent yields and enantioselectivities making use of the novel phosphoramidite I and Pd(dba)2, e.g. 93 % (+)-tert-Bu (R)-2-(4-methoxyphenyl)-4-methylenepyrrolidine-1-carboxylate from CH2:CH(CH2TMS)CH2OAc and 4-MeOC6H4CH:NBoc.
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Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics