Formula: C36H30NO2P. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: (11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine, is researched, Molecular C36H30NO2P, CAS is 415918-91-1, about Unprecedented catalytic enantioselective trapping of arene oxides with dialkylzinc reagents. Author is Bertozzi, Fabio; Crotti, Paolo; Del Moro, Federica; Feringa, Ben L.; Macchia, Franco; Pineschi, Mauro.
The first catalytic enantioselective trapping of sym. and racemic arene oxides with organometallic reagents is reported. Benzene oxide (7-oxabicyclo[4.1.0]hepta-2,4-diene) is in equilibrium with oxepin. Catalyst system included copper ditriflate and (11bR)-N,N-bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine. Thus, the reaction of 7-oxabicyclo[4.1.0]hepta-2,4-diene with dimethylzinc gave (1S,6S)-6-methyl-2,4-cyclohexadien-1-ol in 93% enantiomeric excess and 4-methyl-2,5-cyclohexadien-1-ol. Reactions of 2,3-dihydro-3a,7a-epoxy-1H-indene and 1a,7b-dihydronaphth[1,2-b]oxirene were also investigated.
Here is just a brief introduction to this compound(415918-91-1)Formula: C36H30NO2P, more information about the compound((11bR)-N,N-Bis[(1R)-1-phenylethyl]dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-amine) is in the article, you can click the link below.
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