The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: 6-Bromo-8-methylquinoline(SMILESS: CC1=CC(Br)=CC2=C1N=CC=C2,cas:178396-31-1) is researched.Electric Literature of C11H23Br. The article 《Rhodium(III)-Catalyzed Intermolecular Amidation with Azides via C(sp3)-H Functionalization》 in relation to this compound, is published in Journal of Organic Chemistry. Let’s take a look at the latest research on this compound (cas:178396-31-1).
The amidation reactions of 8-methylquinolines with azides catalyzed by a cationic rhodium(III) complex proceed efficiently to give quinolin-8-ylmethanamine derivatives in good yields via C(sp3)-H bond activation under external oxidant-free conditions. A catalytically competent five-membered rhodacycle has been isolated and characterized, revealing a key intermediate in the catalytic cycle.
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Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics