So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Dillow, G. W.; Gregor, I. K. researched the compound: Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II)( cas:14481-08-4 ).Reference of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II).They published the article 《Gas-phase reactions of bis(dipivaloylmethanato)metal(II) complexes with electrons, halide ions and radicals》 about this compound( cas:14481-08-4 ) in Inorganica Chimica Acta. Keywords: mass spectra dipivaloylmethanato complex reaction; transition metal dipivaloylmethanato gas reaction; cobalt dipivaloylmethanato gas reaction; nickel dipivaloylmethanato gas reaction; copper dipivaloylmethanato gas reaction; zinc dipivaloylmethanato gas reaction; electron reaction transition metal dipivaloylmethanato; halide reaction transition metal dipivaloylmethanato; radical reaction transition metal dipivaloylmethanato. We’ll tell you more about this compound (cas:14481-08-4).
The neg. chem. ionization mass spectra of ML2 (HL = 2,2,6,6-tetramethylheptane-3,5-dione; M = Co, Ni, Cu, Zn], obtained using the halogenated reagent gases, NF3, CF2Cl2 and CF3Br, are presented. Thermalized electrons are captured by ML2 (M = Co, Ni, Cu) to produce mol. ions in which the oxidation state of the metal has been reduced. Lewis acid-base addition of halide ions to the metal to produce adduct ions occurs with all complexes. Reactions between radicals and ML2 also occur to produce adduct mols. which may be ionized by thermalized electrons or halide ions in the same manner as the parent complexes. Halogen radicals react by ligand displacement and homolytic substitution of the ligand while halogenated Me radicals undergo oxidative-addition to the metal. Clustering reactions also occur to produce ions containing 2 metal atoms.
This literature about this compound(14481-08-4)Reference of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II)has given us a lot of inspiration, and I hope that the research on this compound(Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II)) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics