Computed Properties of C10H8BrN. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: 6-Bromo-8-methylquinoline, is researched, Molecular C10H8BrN, CAS is 178396-31-1, about Palladium-Catalyzed sp3 C-H Nitration of 8-Methylquinolines. Author is Zhang, Wei; Ren, Shaobo; Zhang, Jian; Liu, Yunkui.
Palladium-catalyzed nitration of 8-methylquinolines with t-BuONO to give 8-(nitromethyl)quinolines I [R1 = H, 6-Cl, 5-Me, etc; R2 = H, 3-Ph.] in moderate to excellent yields has been developed involving an sp3 C-H bond activation. The resulting (nitromethyl)quinolines could be selectively reduced to (1,2,3,4-tetrahydroquinolin-8-yl)methanamines by NaBH4 in the presence of a catalytic amount of NiCl2·6H2O.
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