Nikitenko, S. I.; Moisy, Ph.; Seliverstov, A. F.; Blanc, P.; Madic, C. published an article about the compound: Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II)( cas:14481-08-4,SMILESS:CC(C)(C1=O[Ni+2]2(O=C(C(C)(C)C)[CH-]1)O=C([CH-]C(C(C)(C)C)=O2)C(C)(C)C)C ).Safety of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:14481-08-4) through the article.
The kinetics of metal β-diketonates sonolysis was studied in hexadecane solutions using a UV/VIS spectrophotometric technique. The following complexes were prepared and studied: Cu(HFAA)2, Cu(DPM)2, Fe(ACAC)3, Ni(DPM)2, Er(DPM)3, Nd(DPM)3, Th(DPM)4, UO2(BTFA)2 · TOPO, and Np(HFAA)4, where HHFAA is hexafluoroacetylacetone, HDPM is dipivaloylmethane, HACAC is acetylacetone, HBTFA is benzoyltrifluoroacetone, and TOPO is trioctylphosphine oxide. Sonolysis was performed under the following conditions: ultrasonic frequency 22 kHz, intensity of ultrasound 3-5 W cm-2, temperature 70-92 °C, Ar atm. The kinetic behavior of the studied complexes are interpreted using a two-site model of the sonochem. processes. In the case of metal β-diketonates with high vapor pressure the sonochem. reactions tend to occur in the gaseous phase of the cavitating bubbles. The sonolysis of less volatile complexes first occur in the liquid reaction zone surrounding the bubbles. Sonication of the studied complexes results in the formation of X-ray amorphous products consisted of a mixture of metal β-diketonates partial degradation products. Heating of as-prepared sonication products in air yields nanocrystalline oxides of corresponding metals.
There is still a lot of research devoted to this compound(SMILES：CC(C)(C1=O[Ni+2]2(O=C(C(C)(C)C)[CH-]1)O=C([CH-]C(C(C)(C)C)=O2)C(C)(C)C)C)Safety of Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)nickel(II), and with the development of science, more effects of this compound(14481-08-4) can be discovered.
Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics