Barsu, Nagaraju; Rahman, Atiur Md.; Sen, Malay; Sundararaju, Basker published the article 《Cp*CoIII-Catalyzed C(sp3)-H Bond Amidation of 8-Methylquinoline》. Keywords: quinolinylmethylamide preparation; methylquinoline oxazolone amidation cobalt catalyst; amidation; cobalt; quinoline; sp3 C−H activation.They researched the compound: 6-Bromo-8-methylquinoline( cas:178396-31-1 ).Quality Control of 6-Bromo-8-methylquinoline. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:178396-31-1) here.
An efficient and external oxidant-free, Cp*CoIII-catalyzed C(sp3)-H bond amidation of 8-methylquinoline, using oxazolone as an efficient amidating agent, is reported for the first time under mild conditions. The reaction is selective and tolerates a variety of functional groups. Based on previous reports and exptl. results, the deprotonation pathway proceeds through an external base-assisted concerted metalation and deprotonation process.
If you want to learn more about this compound(6-Bromo-8-methylquinoline)Quality Control of 6-Bromo-8-methylquinoline, you may wish to communicate with the author of the article,or consult the relevant literature related to this compound(178396-31-1).
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