Yu, Songjie; Tang, Guodong; Li, Yingzi; Zhou, Xukai; Lan, Yu; Li, Xingwei published an article about the compound: 6-Bromo-8-methylquinoline( cas:178396-31-1,SMILESS:CC1=CC(Br)=CC2=C1N=CC=C2 ).Product Details of 178396-31-1. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:178396-31-1) through the article.
Previous direct C-H nitrogenation suffered from simple amidation/amination with limited atom-economy and is mostly limited to C(sp2)-H substrates. In this work, anthranil was designed as a novel bifunctional aminating reagent for both C(sp2)-H and C(sp3)-H bonds under rhodium(III) catalysis, thus affording a nucleophilic aniline tethered to an electrophilic carbonyl, e. g., I. A tridendate rhodium(III) complex has been isolated as the resting state of the catalyst, and DFT studies established the intermediacy of a nitrene species.
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Reference:
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics