Recently I am researching about NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION; FUNCTIONALIZED GEM-DIFLUOROALKENES; DIFLUOROMETHYL 2-PYRIDYL SULFONE; F BOND ACTIVATION; C-F; DIAZO-COMPOUNDS; BIOLOGICAL-ACTIVITY; 4-EXO CYCLIZATIONS; ALKYL-HALIDES; NICKEL, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21772183]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [WK2060190086]; 1000-Youth Talents Plan start-up funding; University of Science and Technology of China. Published in AMER CHEMICAL SOC in WASHINGTON ,Authors: Lin, ZY; Lan, Y; Wang, C. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate. Application In Synthesis of Methyl 3-phenylpropionate
Unactivated alkyl chlorides are abundant building blocks in organic synthesis, but they have been rarely engaged in cross-electrophile coupling. Herein, we report a Ni/Ti-cocatalyzed reductive allylic defluorinative cross -coupling between trifluoromethyl alkenes and unactivated alkyl chlorides and bromides, enabling the efficient preparation of diverse functional-group-rich gem-difluoroalkenes. Notably, synthesis of the gem-difluoroalkene analogues of azaperone, haloperidol, and benperidol was also accomplished using our method as a key step.
Application In Synthesis of Methyl 3-phenylpropionate. Bye, fridends, I hope you can learn more about C10H12O2, If you have any questions, you can browse other blog as well. See you lster.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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