An article Manganese and rhenium-catalyzed selective reduction of esters to aldehydes with hydrosilanes WOS:000574031500010 published article about METHYL BENZOATE; CARBOXYLIC-ACIDS; HYDROSILYLATION REACTIONS; CARBONYL-COMPLEXES; HYDROGENATION; KETONES; MNO/GAMMA-AL2O3; PHOTOCHEMISTRY; MECHANISM; HYDRIDE in [Wei, Duo] Univ Rennes, CNRS, ISCR, UMR 6226, F-35000 Rennes, France; [Wei, Duo; Buhaibeh, Ruqaya; Canac, Yves; Sortais, Jean-Baptiste] Univ Toulouse, UPS, CNRS, LCC CNRS, Toulouse, France; [Sortais, Jean-Baptiste] Inst Univ France, 1 Rue Descartes, F-75231 Paris 05, France in 2020.0, Cited 52.0. Computed Properties of C10H12O2. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3
The selective reduction of esters to aldehydes,viathe formation of stable alkyl silyl acetals, was, for the first time, achieved with both manganese, -Mn-2(CO)(10)- and rhenium -Re-2(CO)(10)- catalysts in the presence of triethylsilane as reductant. These two methods provide a direct access to a large variety of aliphatic and aromatic alkyl silyl acetals (30 examples) and to the corresponding aldehydes (13 examples) upon hydrolysis. The reactions proceeded in excellent yields and high selectivity at room temperature under photo-irradiation conditions (LED, 365 nm, 40 W, 9 h).
Welcome to talk about 103-25-3, If you have any questions, you can contact Wei, D; Buhaibeh, R; Canac, Y; Sortais, JB or send Email.. Computed Properties of C10H12O2
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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