An article Redox-Neutral Nickel(II) Catalysis: Hydroarylation of Unactivated Alkenes with Arylboronic Acids WOS:000565674900001 published article about LINEAR-SELECTIVE HYDROARYLATION; DIRECTING GROUPS; HYDROCARBOFUNCTIONALIZATION; CYCLIZATIONS; PALLADIUM; CLEAVAGE; ETHYLENE; HALIDES in [Wang, Dao-Ming; Feng, Wang; Wu, Yichen; Liu, Tao; Wang, Peng] Chinese Acad Sci, Shanghai Inst Organ Chem, Ctr Excellence Mol Synth, State Key Lab Organomet Chem, 345 Lingling Rd, Shanghai 200032, Peoples R China; [Wang, Peng] Chinese Acad Sci, Shanghai Inst Organ Chem, CAS Key Lab Energy Regulat Mat, 345 Lingling Rd, Shanghai 200032, Peoples R China in 2020.0, Cited 66.0. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4. Quality Control of Methyl 3-phenyl-2-propenoate
Reported here is the discovery of a redox-neutral Ni-II/Ni(II)catalytic cycle which is capable of the linear-selective hydroarylation of unactivated alkenes with arylboronic acids for the first time. This novel catalytic cycle, enabled by the use of an electron-rich diimine ligand, features broad substrate scope, and excellent functional-group and heterocycle compatibility under mild reaction conditions in the absence of additional oxidants and reductants. Mechanistic investigations using kinetic analysis and deuterium-labelling experiments revealed the protonation to be the rate-determining step in this redox-neutral catalysis, and the reversible chain-walking nature of the newly developed diimine-Ni catalyst.
Welcome to talk about 103-26-4, If you have any questions, you can contact Wang, DM; Feng, W; Wu, YC; Liu, T; Wang, P or send Email.. Quality Control of Methyl 3-phenyl-2-propenoate
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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