I found the field of Chemistry very interesting. Saw the article Cobalt-catalyzed direct transformation of aldehydes to esters: the crucial role of an enone as a mediator published in 2019.0. SDS of cas: 103-25-3, Reprint Addresses Liu, DS (corresponding author), Shanxi Univ, Sch Chem & Chem Engn, Taiyuan 030006, Shanxi, Peoples R China.; Xu, BH (corresponding author), Chinese Acad Sci, Inst Proc Engn, State Key Lab Multiphase Complex Syst, Beijing Key Lab Ion Liquids Clean Proc,Key Lab Gr, Beijing 100190, Peoples R China.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate
An oxidative esterification of aldehydes with alkanols catalyzed by an in situ generated low-valent cobalt system has been developed using an enone as a mild oxidant. Mechanistic studies revealed that it proceeds through a Co(i)-catalyzed hydrogen-transfer route, wherein the -vinyl moiety in the bidentate enone functions as a hydride acceptor. Meanwhile, Co(i)-catalyzed formyl C-H activation occurred as a competing reaction leading to aldehyde dimerization. The occurrence of the usually kinetically disfavored hydride transfer step therein was significantly increased in the presence of an enone reacting as a hydride transfer initiator.
SDS of cas: 103-25-3. Welcome to talk about 103-25-3, If you have any questions, you can contact Jiang, BL; Lin, Y; Wang, ML; Liu, DS; Xu, BH; Zhang, SJ or send Email.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics