I found the field of Chemistry very interesting. Saw the article Facile amidation of esters with aromatic amines promoted by lanthanide tris (amide) complexes published in 2020. Recommanded Product: Methyl 3-phenyl-2-propenoate, Reprint Addresses Luo, YJ (corresponding author), Ningbo Univ, Sch Mat Sci & Chem Engn, Ningbo 315211, Peoples R China.; Yao, YM (corresponding author), Soochow Univ, Coll Chem Chem Engn & Mat Sci, Suzhou 215123, Peoples R China.. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate
The development of catalysts capable of catalyzing amidation of esters with amines to construct amides under mild conditions is of great importance. Compared to aliphatic amines, the direct catalytic amidation of esters with less nucleophilic aromatic amines is rather difficult. Employing simple lanthanide tris (amide) complexes Ln[N (SiMe3)(2)](3)(mu-Cl)Li (THF)(3) as the catalysts, it was found a broad range of aromatic amines and esters were efficiently converted into various amides in good yields under mild conditions. A plausible mechanism for this transformation was experimentally supported as starting from an amide exchange reaction between the lanthanide tris (amide) complex and the substrate amine.
Recommanded Product: Methyl 3-phenyl-2-propenoate. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Li, Z; Guo, CJ; Chen, J; Yao, YM; Luo, YJ or concate me.
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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