Tamang, SR; Singh, A; Bedi, D; Bazkiaei, AR; Warner, AA; Glogau, K; McDonald, C; Unruh, DK; Findlater, M in [Tamang, Sem Raj; Singh, Arpita; Bedi, Deepika; Bazkiaei, Adineh Rezaei; Warner, Audrey A.; Glogau, Keeley; McDonald, Corey; Unruh, Daniel K.; Findlater, Michael] Texas Tech Univ, Dept Chem & Biochem, Lubbock, TX 79409 USA published Polynuclear lanthanide-diketonato clusters for the catalytic hydroboration of carboxamides and esters in 2020, Cited 69. Formula: C10H10O2. The Name is Methyl 3-phenyl-2-propenoate. Through research, I have a further understanding and discovery of 103-26-4.
Catalytic reduction of carboxamides into their corresponding amines is an attractive but extremely challenging transformation, which often meets with limited success; the valuable amine products drive ongoing research in this area. Here we show the direct deoxygenation of carboxamides using earth-abundant lanthanum catalysts in the presence of HBpin, presenting good to excellent yields with broad substrate scope and functional group/heteroatom tolerance. Moreover, this method is also effective in catalysing the hydroboration of esters. Finally, selective cleavage of the amide group bonds (C-N versus C-O) could be achieved based on the nature of the nitrogen substituents. Amide reduction via hydroboration is challenging, and catalysts often exhibit limited substrate scope. Here the authors report synthesis of a lanthanum cluster as a catalyst for the hydroboration of esters and amides, capable of reducing a wide range of primary, secondary and tertiary amides to amines.
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Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
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