An article Synthesis, Structural Features, and Hydrogen Adsorption Properties of Three New Flexible Sulfur-Containing Metal-Organic Frameworks WOS:000580511100048 published article about COORDINATION POLYMERS; STORAGE; LIGAND; CO2; SORPTION; LUMINESCENT; SELECTIVITY; MOLECULES in [Montes-Andres, Helena; Orcajo, Gisela; Martos, Carmen; Angel Botas, Juan; Calleja, Guillermo] Rey Juan Carlos Univ, Dept Chem Energy & Mech Technol, Mostoles 28933, Spain; [Leo, Pedro] Rey Juan Carlos Univ, Dept Chem & Environm Technol, Mostoles 28933, Spain; [Rodriguez-Dieguez, Antonio] Univ Granada, Dept Inorgan Chem, Granada, Spain; [Choquesillo-Lazarte, Duane] Univ Granada, Lab Estudios Cristalograf, IACT, CSIC, Granada 18100, Spain in 2020, Cited 62. The Name is Dimethyl 5-aminoisophthalate. Through research, I have a further understanding and discovery of 99-27-4. Recommanded Product: 99-27-4
Three novel flexible sulfur-containing MOF materials named Co-URJC-5, Cu-URJC-6 and Zn-URJC-7, based on the 5,5′-thiodiisophthalic acid linker have been synthesized through solvothermal methods and characterized by different physicochemical techniques. Hydrogen adsorption analysis at room temperature reveals that these compounds display a gate-opening type adsorption mechanism at low pressures, attributed to the flexible nature of the H4TBTC ligand. This behavior is even more noticeable for Cu-URJC-6, since the layer arrangement by p-p stacking interactions between the aromatic layers could contribute to the flexibility of the structure. These results can be considered as a representative example to elucidate how MOF structures are built using flexible ligands and more significantly as a promising route for designing materials with selective gas sorption properties.
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Reference:
Patent; ASTRA ZENECA AB; NPS PHARMACEUTICALS, INC.; WO2004/14881; (2004); A2;,
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