Product Details of 103-25-3. In 2020.0 CHEM SCI published article about REGIOSELECTIVE SYNTHESIS; 4+2 CYCLOADDITION; SUBSTITUTED NAPHTHALENES; CATALYZED BENZANNULATION; O-ALKYNYLBENZALDEHYDES; RING TRANSFORMATION; DERIVATIVES; YNAMIDES; VERSATILE; ANNULATION in [Wu, An; Qian, Hui; Zhao, Wanxiang; Sun, Jianwei] Hong Kong Univ Sci & Technol HKUST, Dept Chem, Kowloon, Clear Water Bay, Hong Kong, Peoples R China; [Wu, An; Qian, Hui; Zhao, Wanxiang; Sun, Jianwei] HKUST Shenzhen Res Inst, 9 Yuexing 1st Rd,Hitech Pk, Shenzhen 518057, Peoples R China in 2020.0, Cited 62.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.
Described here is a modular strategy for the rapid synthesis of beta-functionalized electron-rich naphthalenes, a family of valuable molecules lacking general access previously. Our approach employs an intermolecular benzannulation ofin situgenerated isobenzopyrylium ions with various electron-rich alkynes, which were not well utilized for this type of reaction before. These reactions not only feature a broad scope, complete regioselectivity, and mild conditions, but also exhibit unusual product divergence depending on the substrate substitution pattern. This divergence allows further expansion of the product diversity. Control experiments provided preliminary insights into the reaction mechanism.
Product Details of 103-25-3. About Methyl 3-phenylpropionate, If you have any questions, you can contact Wu, A; Qian, H; Zhao, WX; Sun, JW or concate me.
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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