Recently I am researching about CHEMOSELECTIVE REDUCTION; SECONDARY AMIDES; TERTIARY AMIDES; MILD; ALDEHYDES; ALCOHOLS; COMPLEX; AMINES; HYDROGENATION; HYDROSILANES, Saw an article supported by the National Science FoundationNational Science Foundation (NSF) [CHE-1554906]; Welch FoundationThe Welch Foundation [D-1807]. Recommanded Product: 103-26-4. Published in NATURE RESEARCH in BERLIN ,Authors: Tamang, SR; Singh, A; Bedi, D; Bazkiaei, AR; Warner, AA; Glogau, K; McDonald, C; Unruh, DK; Findlater, M. The CAS is 103-26-4. Through research, I have a further understanding and discovery of Methyl 3-phenyl-2-propenoate
Catalytic reduction of carboxamides into their corresponding amines is an attractive but extremely challenging transformation, which often meets with limited success; the valuable amine products drive ongoing research in this area. Here we show the direct deoxygenation of carboxamides using earth-abundant lanthanum catalysts in the presence of HBpin, presenting good to excellent yields with broad substrate scope and functional group/heteroatom tolerance. Moreover, this method is also effective in catalysing the hydroboration of esters. Finally, selective cleavage of the amide group bonds (C-N versus C-O) could be achieved based on the nature of the nitrogen substituents. Amide reduction via hydroboration is challenging, and catalysts often exhibit limited substrate scope. Here the authors report synthesis of a lanthanum cluster as a catalyst for the hydroboration of esters and amides, capable of reducing a wide range of primary, secondary and tertiary amides to amines.
Recommanded Product: 103-26-4. About Methyl 3-phenyl-2-propenoate, If you have any questions, you can contact Tamang, SR; Singh, A; Bedi, D; Bazkiaei, AR; Warner, AA; Glogau, K; McDonald, C; Unruh, DK; Findlater, M or concate me.
Reference:
Article; Weng, Shiue-Shien; Ke, Chih-Shueh; Chen, Fong-Kuang; Lyu, You-Fu; Lin, Guan-Ying; Tetrahedron; vol. 67; 9; (2011); p. 1640 – 1648;,
Ester – Wikipedia,
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