I found the field of Chemistry very interesting. Saw the article Chemo- and Enantioselective Oxidative alpha-Azidation of Carbonyl Compounds published in 2020.0. SDS of cas: 103-25-3, Reprint Addresses Ishihara, K (corresponding author), Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan.. The CAS is 103-25-3. Through research, I have a further understanding and discovery of Methyl 3-phenylpropionate
We report high-performance I+/H(2)O(2)catalysis for the oxidative or decarboxylative oxidative alpha-azidation of carbonyl compounds by using sodium azide under biphasic neutral phase-transfer conditions. To induce higher reactivity especially for the alpha-azidation of 1,3-dicarbonyl compounds, we designed a structurally compact isoindoline-derived quaternary ammonium iodide catalyst bearing electron-withdrawing groups. The nonproductive decomposition pathways of I+/H(2)O(2)catalysis could be suppressed by the use of a catalytic amount of a radical-trapping agent. This oxidative coupling tolerates a variety of functional groups and could be readily applied to the late-stage alpha-azidation of structurally diverse complex molecules. Moreover, we achieved the enantioselective alpha-azidation of 1,3-dicarbonyl compounds as the first successful example of enantioselective intermolecular oxidative coupling with a chiral hypoiodite catalyst.
About Methyl 3-phenylpropionate, If you have any questions, you can contact Uyanik, M; Sahara, N; Tsukahara, M; Hattori, Y; Ishihara, K or concate me.. SDS of cas: 103-25-3
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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