SDS of cas: 103-25-3. In 2019.0 ORG LETT published article about NUCLEOPHILIC 5-ENDO-TRIG CYCLIZATION; FUNCTIONALIZED GEM-DIFLUOROALKENES; DIFLUOROMETHYL 2-PYRIDYL SULFONE; F BOND ACTIVATION; C-F; DIAZO-COMPOUNDS; BIOLOGICAL-ACTIVITY; 4-EXO CYCLIZATIONS; ALKYL-HALIDES; NICKEL in [Lin, Zhiyang; Lan, Yun; Wang, Chuan] Univ Sci & Technol China, Hefei Natl Lab Phys Sci Microscale, Dept Chem, Ctr Excellence Mol Synth, 96 Jinzhai Rd, Hefei 230026, Anhui, Peoples R China in 2019.0, Cited 107.0. The Name is Methyl 3-phenylpropionate. Through research, I have a further understanding and discovery of 103-25-3.
Unactivated alkyl chlorides are abundant building blocks in organic synthesis, but they have been rarely engaged in cross-electrophile coupling. Herein, we report a Ni/Ti-cocatalyzed reductive allylic defluorinative cross -coupling between trifluoromethyl alkenes and unactivated alkyl chlorides and bromides, enabling the efficient preparation of diverse functional-group-rich gem-difluoroalkenes. Notably, synthesis of the gem-difluoroalkene analogues of azaperone, haloperidol, and benperidol was also accomplished using our method as a key step.
About Methyl 3-phenylpropionate, If you have any questions, you can contact Lin, ZY; Lan, Y; Wang, C or concate me.. SDS of cas: 103-25-3
Reference:
Patent; SANOFI; US2011/294788; (2011); A1;,
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