A new synthetic route of 36692-49-6

According to the analysis of related databases, 36692-49-6, the application of this compound in the production field has become more and more popular.

Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 36692-49-6, name is Methyl 3,4-diaminobenzoate, This compound has unique chemical properties. The synthetic route is as follows., category: esters-buliding-blocks

In a similar manner as described in [1], a solution of amine 2 (1.46 g, 4.20 mmol) in 15 mL MeCN (abs.) was added dropwise at 0 C to a solution of 1,1?-thiocarbonyl diimidazole (1.12 g, 6.30 mmol) and imidazole (94 mg, 1.39 mmol) in 25 mL MeCN (abs.). The reaction mixture was stirred for 1 h at rt. Methyl 3,4-diaminobenzoic acid (1.05 g, 6.30 mmol) was dissolved in 10 mL MeCN (abs.) and added dropwise to the reaction mixture. The solution was stirred for 4 h at 50 C and at rt overnight. The solvent was evaporated at low pressure and the residue purified by column chromatography (n-hexane/ethylacetate 1:1 ? ethyl acetate), yielding 1.83 g (79%) of the product compound as ayellow foam.

According to the analysis of related databases, 36692-49-6, the application of this compound in the production field has become more and more popular.

Reference:
Article; Danneberg, Friederike; Ghidini, Alice; Dogandzhiyski, Plamena; Kalden, Elisabeth; Stroemberg, Roger; Goebel, Michael W.; Beilstein Journal of Organic Chemistry; vol. 11; (2015); p. 493 – 498;,
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