In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 111-79-5, name is Methyl non-2-enoate belongs to esters-buliding-blocks compound, it is a common compound, a new synthetic route is introduced below. Recommanded Product: 111-79-5
[0080] Example 7 – Hydrogenation of esters using complexes 1[0081] tBuOK (15 mg, 0.13 mmol) was added to a solution of complex 1 (51 mg, 0.10 mmol) in 10 mL of THF and the mixture was stirred for 3 min. 1 mL of the obtained solution was mixed with methyl benzoate (2.72 g, 20.0 mol) or other desired substrate in 6 mL of THF or toluene. The mixture was then placed into a 75 mL stainless-steel reactor (Parr 4740) equipped with a magnetic stir bar. The reactor was purged by two cycles of pressurizati on/venting with H2 (150 psi, 10 Bar) and then pressurized with H2 (725 psi, 50 Bar) and disconnected from the H2 source. The reaction was conducted for 1.5 h at 100 C in a preheated oil bath. At the end of the reaction time, the reactor was placed into a cold water bath and it was depressurized after cooling to the ambient temperature. The product benzyl alcohol was obtained after evaporation of all volatiles (THF, CH3OH) under vacuum. The results are shown in tables 1-4 below. See table 2 for a complete list of tested substrates.
The synthetic route of 111-79-5 has been constantly updated, and we look forward to future research findings.
Reference:
Patent; GOUSSEV, Dmitri; SPASYUK, Denis; WO2013/23307; (2013); A1;,
Ester – Wikipedia,
Ester – an overview | ScienceDirect Topics