In an article, author is Shen, Peng, once mentioned the application of 540-10-3, Safety of Hexadecyl palmitate, Name is Hexadecyl palmitate, molecular formula is C32H64O2, molecular weight is 480.85, MDL number is MFCD00053739, category is esters-buliding-blocks. Now introduce a scientific discovery about this category.
Straightforward Synthesis of Succinimide-Fused Pyrrolizidines by A Three-Component Reaction of alpha-Diketone, Amino Acid, and Maleimide
An efficient, one-pot, three-component [3+2] cycloaddition reaction of azomethine ylide obtained from alpha-dicarbonyl compounds (cyclic and acyclic diketone or keto ester) and amino acids with maleimides under catalyst-free conditions has been developed. This cascade protocol shows high efficiency and remarkable functional group tolerance, and the ubiquitous succinimide-fused pyrrolizidines with a highly compact and strained scaffold were obtained with high yield and excellent diastereoselectivity. Furthermore, this novel and atom-economical strategy could be performed on a gram scale with comparable reaction efficiency.
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