A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 94-60-0, Name is Dimethyl cyclohexane-1,4-dicarboxylate, molecular formula is C10H16O4. In an article, author is Song, Xia,once mentioned of 94-60-0, Formula: C10H16O4.
Synthesis of 1,3-Benzodiazepines through [5+2] Annulation of N-Aryl Amidines with Propargylic Esters
In this paper, an efficient synthesis of functionalized 1,3-benzodiazepines through an unprecedented [5 + 2] annulation of N-aryl amidines with propargylic esters is presented. The reactions proceed through Rh(III)-catalyzed C(sp(2))-H alkenylation followed by annulation and deacetoxylation along with cascade C-H/N-H/C-O bond cleavage and C-C/C-N bond formation. Furthermore, the cytotoxicity of selected products against several human cancer cell lines was tested, which demonstrated their good potential for pharmaceutical applications.
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