Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 10233-13-3, Name is Isopropyl dodecanoate, molecular formula is C15H30O2. In an article, author is Mohri, Tomoyo,once mentioned of 10233-13-3, SDS of cas: 10233-13-3.
Stereocontrolled Total Synthesis of (-)-Isocelorbicol and Its Elaboration to Natural Dihydro-beta-agarofuran Esters
The first total synthesis of four naturally occurring dihydro-beta-agarofuran esters has been accomplished via a highly stereocontrolled 14-step access to their common core triol, (-)-isocelorbicol. A semipinacol rearrangement of an epoxy alcohol to install a quaternary carbon, diastereoselective conjugate reduction of a spirocyclic butenolide for the establishment of a methyl-bearing chiral center, and ring-closing metathesis to construct the decalin ring system were exploited as the key steps for the high-yielding synthesis of (-)-isocelorbicol.
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