Related Products of 106-65-0, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 106-65-0, Name is Dimethyl succinate, SMILES is O=C(OC)CCC(OC)=O, belongs to esters-buliding-blocks compound. In a article, author is Mizoguchi, Haruki, introduce new discover of the category.
Synthesis of functionalized cyclopropylboronic esters based on a 1,2-metallate rearrangement of cyclopropenylboronate
A procedure converting tribromocyclopropane to densely functionalized beta-selenocyclopropylboronic ester using the 1,2-metallate rearrangement of a boron ate-complex has been developed. Treatment of an in situ-generated cyclopropenylboronic ester ate-complex with phenylselenenyl chloride triggered stereospecific rearrangement to produce functionalized cyclopropanes. DFT calculations for 1,2-metallate rearrangement suggested that the reaction proceeds through a seleniranium intermediate.
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