The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Computed Properties of C8H16O4, 6065-82-3, Name is Ethyl diethoxyacetate, SMILES is O=C(OCC)C(OCC)OCC, in an article , author is Nie, Kaili, once mentioned of 6065-82-3.
Enzymatic Hydration of Linoleic Acid Followed with Selective Chain Cleavage for Biofuels and Biomaterials Production
Oils and fats are important feedstock for industrial processes. Due to the carbon efficiency limitation, the progress of chain cleavage production of value-added chemicals was however restricted. From the previous studies, it was found that fatty acids with beta-hydroxyolefin structure could be thermally cleaved into value-added products effectively. The hydratase catalyzed regio-selective hydration is the key step for the synthesis of beta-hydroxyolefin structured fatty acid. In this research, the hydratase form Lactobacillus acidophilus was chosen as enzymatic catalyst, and both the expression conditions for the recombined protein in E. coli, and the hydration reaction conditions were optimized. The yield of 10-hydroxy-12-octadecenoic acid (HOD) achieved 85% under optimum hydration conditions. At the same time, the thermal rearrangement reaction of 10-HOD was also preliminary investigated in this research. Value-added chemicals of alpha-octene and 10-oxo-decanoic acid (ODA) were obtained through the thermal cleavage. From this process, a high efficiency carbon production pathway with great potential for producing high value-added chemicals from unsaturated fatty acid was presented.
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