Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Andler, Oliver, once mentioned the application of 99548-55-7, Name is Methyl 4-bromo-2-methylbenzoate, molecular formula is C9H9BrO2, molecular weight is 229.07, MDL number is MFCD09954957, category is esters-buliding-blocks. Now introduce a scientific discovery about this category, Recommanded Product: Methyl 4-bromo-2-methylbenzoate.
A Straightforward Synthesis of Polyketides via Ester Dienolate Matteson Homologation
Application of ester dienolates as nucleophiles in Matteson homologations allows for the stereoselective synthesis of highly substituted alpha,beta-unsaturated delta-hydroxy carboxyl acids, structural motifs widespread found in polyketide natural products. The protocol is rather flexible and permits the introduction of substituents and functionalities also at those positions which are not accessible by the commonly used aldol reaction. Therefore, this ester dienolate Matteson approach is an interesting alternative to the classical polyketide syntheses.
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