Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 111-82-0, Name is Methyl laurate, molecular formula is C13H26O2. In an article, author is Pandey, Madhusudan K.,once mentioned of 111-82-0, Name: Methyl laurate.
Ester Hydrogenation with Bifunctional Metal-NHC Catalysts: Recent Advances
Hydrogenation of ester to alcohol is an essential reaction in organic chemistry due to its importance in the production of a wide range of bulk and fine chemicals. There are a number of homogeneous and heterogeneous catalyst systems reported in the literature for this useful reaction. Mostly, phosphine-based bifunctional catalysts, owing to their ability to show metal-ligand cooperation during catalytic reactions, are extensively used in these reactions. However, phosphine-based catalysts are difficult to synthesize and are also highly air- and moisture-sensitive, restricting broad applications. In contrast, N-heterocyclic carbenes (NHCs) can be easily synthesized, and their steric and electronic attributes can be fine-tuned easily. In recent times, many phosphine ligands have been replaced by potent sigma-donor NHCs, and the resulting bifunctional metal-ligand systems are proven to be very efficient in several important catalytic reactions. This mini-review focuses the recent advances mainly on bifunctional metal -NHC complexes utilized as (pre)catalysts in ester hydrogenation reactions.
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