Chemistry, like all the natural sciences, begins with the direct observation of nature¡ª in this case, of matter.111-82-0, Name is Methyl laurate, SMILES is CCCCCCCCCCCC(OC)=O, belongs to esters-buliding-blocks compound. In a document, author is Kua, Jeremy, introduce the new discover, Name: Methyl laurate.
Early Steps of Glycolonitrile Oligomerization: A Free-Energy Map
Building on our previous free-energy map (J. Phys. Chem. A 2018, 122, 6769-6779) examining the reactions of monomeric glycolonitrile, we explore the formation of its dimers and trimers in aqueous solution under neutral conditions. While 5-membered rings are kinetically favored, open-chain oligomers with ester or amide linkages are thermodynamically favored. Accessing the 5-membered rings also provides a potential route to glyoxal that bypasses preforming glycolamide, the thermodynamic sink for monomers. However, finding a kinetically accessible route to glycine starting from glycolonitrile in the absence of added ammonia at room temperature proved challenging; the best case involved an intramolecular nucleophilic substitution reaction in a dimer containing neighboring imine and amide groups. Our free-energy map also examines routes to experimentally proposed moieties, explaining why some are observed in low yield or not at all.
The proportionality constant is the rate constant for the particular unimolecular reaction. the reaction rate is directly proportional to the concentration of the reactant. I hope my blog about 111-82-0 is helpful to your research. Name: Methyl laurate.