Chemo-enzymatic cascade processes are invaluable due to their ability to rapidly construct high-value products from available feedstock chemicals in a one-pot relay manner. In an article, author is Xu, Jian-Xing, once mentioned the application of 106-33-2, Name is Ethyl Laurate, molecular formula is C14H28O2, molecular weight is 228.37, MDL number is MFCD00015065, category is esters-buliding-blocks. Now introduce a scientific discovery about this category, Computed Properties of C14H28O2.
NHC ligand-powered palladium-catalyzed carbonylative C-S bond cleavage of vinyl sulfides: efficient access to tert-butyl arylacrylates
A method for palladium-catalyzed carbonylative C-S bond activation of divinyl sulfides to synthesize numerous tert-(E)-butyl arylacry-lates under 1 bar of CO has been developed. Employing electron-rich NHC as the ligand, the electron-rich and stabilized palladium complex trend to oxidative addition to the relatively inert C-S bond and decreased the poisoning effect of sulfide and CO; a series of tert-(E)-butyl acrylates were obtained in moderate to good yields.
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