The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Application In Synthesis of Ethyl nonanoate, 123-29-5, Name is Ethyl nonanoate, SMILES is CCCCCCCCC(OCC)=O, in an article , author is Liang, Xiao, once mentioned of 123-29-5.
Copper/Palladium Bimetallic System for the Synthesis of Isobenzofuranones through [4+1] Annulation between Propiophenones and Benzoic Acids
A copper/palladium-catalyzed annulation from benzoic acids and propiophenones for the synthesis of isobenzofuranones was reported. The Cu-(2,2,6,6-tetramethylpiperidin-1-yl)oxyl system showed a great ability to activate the C-H bond on the alpha- and beta-carbons of a carbonyl group, and the in situgenerated enone intermediate in this reaction could be further transformed to construct isobenzofuranones with the catalysis of Pd(dba)(2) (dba = dibenzylideneacetone). Various isobenzofuranones could be obtained in moderate to good yields, and a great atom economy was highlighted by utilizing this method.
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