The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature. Name: Chloromethyl isopropyl carbonate, 35180-01-9, Name is Chloromethyl isopropyl carbonate, SMILES is O=C(OCCl)OC(C)C, in an article , author is Marschner, Stefan M., once mentioned of 35180-01-9.
Modular Synthesis of trans-A(2)B(2)-Porphyrins with Terminal Esters: Systematically Extending the Scope of Linear Linkers for Porphyrin-Based MOFs
Differently functionalized porphyrin linkers represent the key compounds for the syntheses of new porphyrin-based metal-organic frameworks (MOFs), which have gathered great interest within the last two decades. Herein we report the synthesis of a large range of 5,15-bis(4-ethoxycarbonylphenyl)porphyrin derivatives, through Suzuki and Sonogashira cross-coupling reactions of an easily accessible corresponding meso-dibrominated trans-A(2)B(2)-porphyrin with commercially available boronic acids or terminal alkynes. The resulting porphyrins were fully characterized through NMR, MS, and IR spectroscopy and systematically investigated through UV/Vis absorption. Finally, selected structures were saponified to the corresponding carboxylic acids and subsequently proven to be suitable for the synthesis of surface-anchored MOF thin films.
But sometimes, even after several years of basic chemistry education, it is not easy to form a clear picture on how they govern reactivity! 35180-01-9, you can contact me at any time and look forward to more communication. Name: Chloromethyl isopropyl carbonate.