111-82-0, A common heterocyclic compound, 111-82-0, name is Methyl laurate, molecular formula is C13H26O2, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc, below Introduce a new synthetic route.
laurateMethyl laurate (99.4%, 870 mg, Wako Pure Chemical Industries,Ltd.), Ru-Sn-Mo/C catalyst (43 mg), Fe (28 mmol (1564 mg)of 60-80 nm particles without previous activation), H2O(28-83 mmol), and tetradecane were introduced into a 100 mLHastelloy C high pressure reactor. After purging the reactor fourtimes with nitrogen, it was heated to the required temperatureand maintained at that state for 1-24 h. The stirring rate wasadjusted to 1000 rpm. The resulting products were separated bycentrifugation and filtration, and their yields were determinedby gas chromatography on an instrument equipped with a flameionization detector (Shimadzu, GC-2014) using anisole as aninternal standard. A capillary column (Restek, Stabilwax) wasused to analyze the esters, alcohols, acids, and higher molecularweight hydrocarbons. The conversion of methyl laurate and yieldof product were defined as follows:
The synthetic route of 111-82-0 has been constantly updated, and we look forward to future research findings.
Reference:
Article; Sagata, Kunimasa; Hirose, Mina; Hirano, Yoshiaki; Kita, Yuichi; Applied Catalysis A: General; vol. 523; (2016); p. 85 – 91;,
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